Condensed-Phase Effects on the Structual Properties of C6H6CH2CN-SiF4 and CH3CH2CN-SiF4
Loading...
Files
Date
Authors
Hora, Nicholas J.
Advisors
License
DOI
Type
Presentation
Journal Title
Journal ISSN
Volume Title
Publisher
Grantor
Abstract
Our research involves the identification of molecular complexes that change structure when the chemical environment is altered, e.g., gas-phase to solid-state. The plot conveys a general mechanism for bulk condensed-phase effects. The key is a long bond length in the gas phase with a very slight energy rise towards the shorter donor-acceptor distances. The addition of solvation energies can shift the bond length inward.
Description
Color poster with text, models, and graphs.
Keywords
Related Material and Data
Citation
Sponsorship
National Science Foundation; MERCURY Consortium; ACS-PRF, University of Wisconsin--Eau Claire Office of Research and Sponsored Programs.